fig2

180° head-to-head flat domain walls in single crystal BiFeO<sub>3</sub>

Figure 2. (A) Low magnification BF-STEM image of a ($$\overline{1}$$10) FIB-prepared lamella. The dark arrow at the thin edge of the lamella points towards increasing thickness. The width of the straight dark lines is independent of specimen thickness, showing that they correspond to planes seen edge-on. The crystal orientation applies to all images in this figure. (B) Ideal ($$\overline{1}$$10) projection of BiFeO3, where Bi atoms are presented in red, Fe blue, and O grey. The direction of the -δFB vector is also shown. (C) A high-resolution ABF-STEM image of a flat wall. White lines are aligned horizontally and vertically, allowing the rigid-body displacement of the domains along [110] and [001] to be seen. (D) An ADF-STEM image taken simultaneously with C). Arrows in (D) show local -δFB vectors, indicating the magnitude and direction of polarisation in each unit cell.

Microstructures
ISSN 2770-2995 (Online)
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