fig6

Direct Z-scheme photocatalytic systems based on vdW heterostructures for water splitting and CO<sub>2</sub> reduction: fundamentals and recent advances

Figure 6. (A) TEM images of (a) BCN, (b) CN and (c) CN/BCN-0.5% samples; (d-g)TEM EDX elemental mappings of CN/BCN-0.5% sample. (Reproduced with permission[39]. Copyright 2020, Elsevier); (B) H2 production rate of different samples of CN/BCN heterostructures under the visible light (λ > 420 nm). (Reproduced with permission[39]. Copyright 2020, Elsevier); (C) Wavelength-dependent AQE of CN/BCN-0.5% sample. (Reproduced with permission[39]. Copyright 2020, Elsevier); (D) The electron-hole recombination and electron and hole transfer dynamics in C7N6/Sc2CCl2 heterostructures, where the time constants are fitted by the exponential function corresponding to three processes. (Reproduced with permission[40]. Copyright 2022, American Chemical Society); (E) Charge transfer in C7N6/Sc2CCl2 heterostructure. (Reproduced with permission[40]. Copyright 2022, American Chemical Society); (F) Processes occurring on the C7N6/Sc2CCl2 surface at pH 7. The blue and orange short lines stand for intermediate states in HER/OER processes on the undoped heterostructure with or without light-induced bias potential U, whereas the green and purple short lines stand for intermediate states in the OER processes occurring on the doped S atom. (Reproduced with permission[40]. Copyright 2022, American Chemical Society).

Microstructures
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